This discussion on Toluene reacts with excess of Cl2 in the presence of sunlight to give a product which on hydrolysis followed by the reaction with NaOH givea)b)c)d)None of theseCorrect answer is option 'C'. Explanation: The reaction of Cl 2, in presence of FeCl 3, with benzene yields a ring substitution product.. CH2Br. , (B) Ac,O is used to acylate-OH group You've reached the end of your free preview. For example, propane has eight hydrogens, six of them being structurally equivalent primary… 8 [25 Marks] Total = 50 Marks 9. You can study other questions, MCQs, videos and tests for NEET on EduRev and even discuss your questions like
Toluene reacts with excess of Cl2 in presence of (b) It involves R-OPOCl, with --OPOCl, as a better Answer: d. 7) Reaction of 1,3-dimethylbenzene with tert-butyl chloride in presence of AlCl 3 occurs primarily at carbon 5 because: a) Methyl groups are ring deactivating towards electrophilic aromatic substitution. A perfect rating awaits for the person who answers. Innov8 Coworking Kurla, 2nd Floor, Piramal Agastya Pvt. The reaction of toluene with Cl2 in presence of FeCl3 gives predominantly Hydrocarbons Organic Halogens The reaction of toluene with Cl 2 in presence of FeCl 3 gives predominantly. A substituted aromatic ring like toluene does react with a halogen like bromine under opportune conditions: more precisely, substitution occurs at the H atoms on the aromatic ring itself. d) Only monosubstitution is possible when toluene reacts with excess of alkyl chloride in presence of AlCl 3. Substitution reactions. pyridine Toluene reacts with excess of in presence of sunlight to give a product which on hydrolysis followed by reaction with NaOH give. Amine is obtained as major product in Sulfonation of Benzene Benzene will react with sulfur trioxide, and in the presence of an acid, aryl sulfonic acids are produced. community of NEET. The reactions happen at room temperature. Dehydration of alcohols takes place more more rapidly reaction. which-OPOCL, is leaving COONa 2.5k LIKES. leaving group All the materials and services in the Kunduz application is provided for educational purposes. major product in zo is At ordinary condition 1:1 mixture of conc HNO3 and. Solution : 
. The periodic table, physical constants and relative atomic masses needed for these problems are given on the inside covers of Chemistry, fourth edition by C.E. statement(s) about the following dehydration, 75. Toluene reacts with excess of Cl2 in the presence of sunlight to give a product which on hydrolysis followed by the reaction with NaOH givea)b)c)d)None of theseCorrect answer is option 'C'. soon. This page gives you the facts and a simple, uncluttered mechanism for the free radical substitution reaction between methylbenzene (previously known as toluene) and chlorine. CH3 NBS(1 mole) sunlight. LiAIHA 400+ VIEWS. NO2. If you want the mechanism explained to you in … The reaction of benzene with $\ce{Cl2}$ in presence of sunlight breaks the double bonds and 6 chlorine atoms attach to the ring. POC13 -NH-CH with POCI, than with H2SO4. The alkanes and cycloalkanes, with the exception of cyclopropane, are probably the least chemically reactive class of organic compounds. (d) It is El reaction without formation of carbocation The halogenation of benzene. However, when the reaction is light-catalyzed with no Fe 3+ catalyst present, the product is C 6 H 5 CH 2 Cl. In organic chemistry, free-radical halogenation is a type of halogenation.This chemical reaction is typical of alkanes and alkyl-substituted aromatics under application of UV light.The reaction is used for the industrial synthesis of chloroform (CHCl 3), dichloromethane (CH 2 Cl 2), and hexachlorobutadiene.It proceeds by a free-radical chain mechanism.
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